Basic physical properties of cubic boron arsenide
Abstract
Cubic boron arsenide (BAs) is an emerging semiconductor material with a record-high thermal conductivity subject to intensive research interest for its applications in electronics thermal management. However, many fundamental properties of BAs remain unexplored experimentally since high-quality BAs single crystals have only been obtained very recently. Here, we report the systematic experimental measurements of important physical properties of BAs, including the bandgap, optical refractive index, elastic modulus, shear modulus, Poisson's ratio, thermal expansion coefficient, and heat capacity. In particular, light absorption and Fabry–Pérot interference were used to measure an optical bandgap of 1.82 eV and a refractive index of 3.29 (657 nm) at room temperature. A picoultrasonic method, based on ultrafast optical pump probe spectroscopy, was used to measure a high elastic modulus of 326 GPa, which is twice that of silicon. Furthermore, temperature-dependent X-ray diffraction was used to measure a linear thermal expansion coefficient of 3.85 × 10−6 K−1; this value is very close to prototype semiconductors such as GaN, which underscores the promise of BAs for cooling high power and high frequency electronics. We also performed ab initio theory calculations and observed good agreement between the experimental and theoretical results. Importantly, this work aims to build a database (Table I) for the basic physical properties of BAs with the expectation that this semiconductor will inspire broad research and applications in electronics, photonics, and mechanics.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Sep 16, 2019
- Source ID
- 10.1063/1.5116025
Entities
People
- Huan Wu
- Huuduy Nguyen
- Joon Sang Kang
- Man Li
- Yongjie Hu
Organizations
- Air Force Office of Scientific Research
- Alfred P. Sloan Foundation
- American Chemical Society Petroleum Research Fund
- National Science Foundation
- University of California, Los Angeles