First-principles study of antisite defects in perovskite stannates

Abstract

The perovskite stannates BaSnO3 and SrSnO3 are being actively explored for applications as transparent conductors, in power or high-frequency electronics, and as channel materials in epitaxial integration with functional perovskites. Realizing these applications requires controlled n-type doping, i.e., avoiding the formation of compensating acceptor-type defects. Here, we use density-functional theory to examine the formation of cation antisite defects. Our results indicate that antisites are not a problem in BaSnO3; however, in SrSnO3, SrSn antisites may act as compensating centers.

Document Details

Document Type
Pub Defense Publication
Publication Date
Nov 15, 2019
Source ID
10.1063/1.5126206

Entities

People

  • Andrew Rowberg
  • Chris G. Van de Walle
  • L. Weston
  • Santosh Kc

Organizations

  • Lawrence Berkeley National Laboratory
  • National Science Foundation
  • Office of Naval Research
  • San José State University

Tags

Fields of Study

  • Materials science

Readers

  • Database Systems and Applications
  • Semiconductor Device Technology
  • Solar Photovoltaics and Thermoelectric Devices.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene