Clean, robust alkali sources by intercalation within highly oriented pyrolytic graphite

Abstract

We report the fabrication, characterization, and use of rubidium vapor dispensers based on highly oriented pyrolytic graphite (HOPG) intercalated with metallic rubidium. Compared to commercial chromate salt dispensers, these intercalated HOPG (IHOPG) dispensers hold an order of magnitude more rubidium in a similar volume, require less than one-fourth the heating power, and emit less than one-half as many impurities. Appropriate processing permits exposure of the IHOPG to atmosphere for over ninety minutes without any adverse effects. Intercalation of cesium, potassium, and lithium into HOPG has also been demonstrated in the literature, which suggests that IHOPG dispensers may also be made for those metals.

Document Details

Document Type
Pub Defense Publication
Publication Date
Mar 01, 2020
Source ID
10.1063/1.5128120

Entities

People

  • Benjamin K Stuhl
  • Brian L. Kasch
  • David A. Hostutler
  • Eric A Imhof
  • Mary Spanjers
  • Matthew B Squires
  • Matthew S. Bigelow
  • Rudolph N Kohn
  • Spencer E. Olson

Organizations

  • Air Force Research Laboratory
  • Space Dynamics Laboratory

Tags

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Electrochemical Surface Science
  • Software Engineering