Molecular beam homoepitaxy on bulk AlN enabled by aluminum-assisted surface cleaning

Abstract

We compare the effectiveness of in situ thermal cleaning with that of Al-assisted cleaning of native surface oxides of bulk AlN for homoepitaxial growth by molecular beam epitaxy. Thermal deoxidation performed at 1450 °C in vacuum results in voids in the AlN substrate. On the other hand, Al-assisted deoxidation at ≈900°C results in high-quality AlN homoepitaxy, evidenced by clean and wide atomic terraces on the surface and no extended defects at the growth interface. This study shows that Al-assisted in situ deoxidation is effective in removing native oxides on AlN, providing a clean surface to enable homoepitaxial growth of AlN and its heterostructures; furthermore, it is more attractive over thermal deoxidation, which needs to be conducted at much higher temperatures due to the strong bonding strength of native oxides on AlN.

Document Details

Document Type
Pub Defense Publication
Publication Date
Apr 27, 2020
Source ID
10.1063/1.5143968

Entities

People

  • Celesta S. Chang
  • David A. Muller
  • Debdeep Jena
  • Huili Grace Xing
  • Kazuki Nomoto
  • Kevin Lee
  • L. J. Schowalter
  • Masato Toita
  • Mingli Gong
  • Yong-Jin Cho

Organizations

  • Air Force Office of Scientific Research
  • Cornell University
  • National Science Foundation

Tags

Fields of Study

  • Materials science

Readers

  • Electrical Engineering
  • Semiconductor Device Technology