Long-wave infrared scattering spectra and modeling of trace particles on surfaces for standoff detection

Abstract

We experimentally measure the scattered reflectance of particles deposited on smooth substrates with a mid-wave to long-wave supercontinuum source and a FTIR based sensor at 3.6 m. We measure the scattering return from sparse particles of 1,3,5-Trinitroperhydro-1,3,5-triazine, caffeine, and acetaminophen deposited on smooth aluminum, silicon, and glass substrates. We also measure mono-disperse 5.4, 10.8, and 19.4 μm diameter polystyrene spheres deposited on aluminum. We demonstrate that spectra obtained using our supercontinuum FTIR sensor can be accurately simulated using a Bobbert–Vlieger model, and non-spherical particle spectra can be approximated by spherical results. The Bobbert–Vlieger model can then be used to create a library that can account for the trace chemical and underlying substrate for standoff chemical identification.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jun 23, 2020
Source ID
10.1063/5.0009463

Entities

People

  • Agustin I. Ifarraguerri
  • Fred L Terry
  • Kaiwen Guo
  • Mohammed N. Islam
  • Ramon A Martinez
  • Tianqu Zhai

Organizations

  • Intelligence Advanced Research Projects Activity
  • University of Michigan

Tags

Fields of Study

  • Physics

Readers

  • Aerosol Science/Aerosol Physics
  • Image Processing and Computer Vision.
  • Nanoscale Plasmonic Nanotechnology