Light emission from plasmonic nanostructures
Abstract
The mechanism of light emission from metallic nanoparticles has been a subject of debate in recent years. Photoluminescence and electronic Raman scattering mechanisms have both been proposed to explain the observed emission from plasmonic nanostructures. Recent results from Stokes and anti-Stokes emission spectroscopy of single gold nanorods using continuous wave laser excitation carried out in our laboratory are summarized here. We show that varying excitation wavelength and power change the energy distribution of hot carriers and impact the emission spectral lineshape. We then examine the role of interband and intraband transitions in the emission lineshape by varying the particle size. We establish a relationship between the single particle emission quantum yield and its corresponding plasmonic resonance quality factor, which we also tune through nanorod crystallinity. Finally, based on anti-Stokes emission, we extract electron temperatures that further suggest a hot carrier based mechanism. The central role of hot carriers in our systematic study on gold nanorods as a model system supports a Purcell effect enhanced hot carrier photoluminescence mechanism. We end with a discussion on the impact of understanding the light emission mechanism on fields utilizing hot carrier distributions, such as photocatalysis and nanothermometry.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Aug 09, 2021
- Source ID
- 10.1063/5.0053320
Entities
People
- Behnaz Ostovar
- Lawrence J Tauzin
- Stephan Link
- Stephen Lee
- Yi-Yu Cai
Organizations
- 3M
- Air Force Office of Scientific Research
- American Chemical Society Petroleum Research Fund
- National Science Foundation
- Office of Naval Research
- Rice University
- Robert A. Welch Foundation