Molecular beam homoepitaxy of N-polar AlN on bulk AlN substrates

Abstract

N-polar AlN epilayers were grown on the N-face of single-crystal bulk AlN substrates by plasma-assisted molecular beam epitaxy. A combination of in situ thermal deoxidation and Al-assisted thermal desorption at high temperature aided in removing native surface oxides and impurities from the N-polar surface of the substrate enabling successful homoepitaxy. Subsequent epitaxial growth of the AlN layer on the in situ cleaned substrates, grown in a sufficiently high Al droplet regime, exhibited smooth surface morphologies with clean and wide atomic steps. KOH etch studies confirmed the N-polarity of the homoepitaxial films. Secondary ion mass spectrometry profiles show Si and H impurity concentrations below the noise levels, whereas O and C impurity concentrations of ∼8×1017 and ∼2×1017 atoms/cm3 are observed, respectively. Although the structural defect densities are low, they interestingly appear as inversion domains of different dimensionalities.

Document Details

Document Type
Pub Defense Publication
Publication Date
Sep 01, 2022
Source ID
10.1063/5.0100225

Entities

People

  • Debdeep Jena
  • Huili Grace Xing
  • Jashan Singhal
  • Jimy Encomendero Risco
  • Kazuki Nomoto
  • Len van Deurzen
  • Masato Toita
  • Yong-Jin Cho
  • Zexuan Zhang

Organizations

  • Air Force Office of Scientific Research
  • Asahi Kasei
  • Cornell University
  • National Science Foundation
  • Semiconductor Research Corporation
  • United States Department of Energy

Tags

Fields of Study

  • Materials science

Readers

  • Semiconductor Device Technology