Computational study of defect complexes in β-LiGaO2 and their relation to the donor–acceptor-pair recombination

Abstract

Hybrid functional calculations are presented for defects in LiGaO2 with the fraction of non-local exchange adjusted to reproduce the recently reported exciton gap of 6.0 eV. We study how the defect transition levels of the main native defects change with respect to the band edges compared to earlier calculations which assumed a smaller bandgap near 5.1 eV. In addition, we consider defect complexes formed by combining the main native donor GaLi with the main acceptors, VLi and LiGa antisites as a function of their relative position. These results are used to tentatively identify the photoluminescence bands previously assigned to donor–acceptor-pair recombination.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jun 08, 2023
Source ID
10.1063/5.0146981

Entities

People

  • Adisak Boonchun
  • Klichchupong Dabsamut
  • Walter R. L. Lambrecht

Organizations

  • Air Force Office of Scientific Research
  • Case Western Reserve University
  • Kasetsart University

Tags

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.

Technology Areas

  • Microelectronics