Ultrasensitive gas detection of large-area boron-doped graphene

Abstract

The gas-sensing performance of graphene could be remarkably enhanced by incorporating dopants into its lattice based on theoretical calculations. However, to date, experimental progress on boron-doped graphene (BG) is still very scarce. Here, we achieved the controlled growth of large-area, high-crystallinity BG sheets and shed light on their electronic features associated with boron dopants at the atomic scale. As a proof-of-concept, it is demonstrated that boron doping in graphene could lead to a much enhanced sensitivity when detecting toxic gases (e.g. NO 2 ). Our results will open up new avenues for developing high-performance sensors able to detect trace amount of molecules. In addition, other new fascinating properties can be exploited based on as-synthesized large-area BG sheets.

Document Details

Document Type
Pub Defense Publication
Publication Date
Nov 02, 2015
Source ID
10.1073/pnas.1505993112

Entities

People

  • Amber McCreary
  • Ana Laura Elias
  • Andrés Botello-méndez
  • Avetik R. Harutyunyan
  • David A Cullen
  • Feiyu Kang
  • Gugang Chen
  • Jean-christophe Charlier
  • Kazunori Fujisawa
  • Konstantin S. Novoselov
  • Liangbo Liang
  • Mauricio Terrones
  • Minghu Pan
  • Morinobu Endo
  • Nestor Perea-lopez
  • Qing Li
  • Rodolfo Cruz-Silva
  • Ruitao Lv
  • Sergey V. Morozov
  • Simin Feng
  • Vincent Meunier
  • Xavier Declerck

Organizations

  • Air Force Office of Scientific Research
  • Army Research Office
  • European Commission
  • Honda R&D Americas
  • Huazhong University of Science and Technology
  • Japan Science and Technology Agency
  • National Fund for Scientific Research
  • National Natural Science Foundation of China
  • Oak Ridge National Laboratory
  • Pennsylvania State University
  • Rensselaer Polytechnic Institute
  • Shinshu University
  • Soochow University
  • Tsinghua University
  • UCLouvain
  • University of Manchester

Tags

Readers

  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene