Highly active catalyst derived from a 3D foam of Fe(PO 3 ) 2 /Ni 2 P for extremely efficient water oxidation

Abstract

The oxygen evolution reaction (OER) is a sluggish reaction with poor catalytic efficiency, which is one of the major bottlenecks in realizing water splitting, CO 2 reduction, and rechargeable metal–air batteries. In particular, the commercial utilization of water electrolyzers requires an exceptional electrocatalyst that has the capacity of delivering ultra-high oxidative current densities above 500 mA/cm 2 at an overpotential below 300 mV with long-term durability. Few catalysts can satisfy such strict criteria. Here we report a promising oxygen-evolving catalyst with superior catalytic performance and long-term durability; to the best of our knowledge, it is one of the most active OER catalysts reported thus far that satisfies the criteria for large-scale commercialization of water–alkali electrolyzers.

Document Details

Document Type
Pub Defense Publication
Publication Date
May 15, 2017
Source ID
10.1073/pnas.1701562114

Entities

People

  • Ching-Wu Chu
  • Fang Yu
  • Haiqing Zhou
  • Jingying Sun
  • Ran He
  • Shuo Chen
  • Zhifeng Ren

Organizations

  • Air Force Office of Scientific Research
  • Defense Threat Reduction Agency
  • Lawrence Berkeley National Laboratory
  • United States Department of Energy
  • University of Houston

Tags

Readers

  • Distributed Systems and Data Platform Development
  • Electrochemical Engineering/ Fuel Cell Technologies

Technology Areas

  • Microelectronics