Catalyst discovery through megalibraries of nanomaterials

Abstract

Discovering new materials is traditionally a slow process, as the materials genome encompasses a massive parameter space, particularly on the nanoscale where synthesis methods are less universal. To overcome this challenge, a cantilever-free lithography method has been used to deposit millions of discrete nanoreactors on a substrate, which can be transformed into millions of nanoparticles spatially encoded in terms of composition and size. These compositions were screened for their ability to catalytically grow carbon nanotubes, and a composition (Au 3 Cu) was identified as optimum for this application. More generally, this combinatorial method of synthesizing nanoparticle megalibraries offers researchers a platform for identifying structures with desired properties at a rate not previously possible.

Document Details

Document Type
Pub Defense Publication
Publication Date
Dec 17, 2018
Source ID
10.1073/pnas.1815358116

Entities

People

  • Benji Maruyama
  • Brian Meckes
  • Chad Mirkin
  • Edward J Kluender
  • James L. Hedrick
  • Jingshan Du
  • Keith A Brown
  • Liane M. Moreau
  • Rahul Rao

Organizations

  • Air Force Office of Scientific Research
  • Air Force Research Laboratory
  • Air Force Research Laboratory Information Directorate
  • Division of Electrical, Communications & Cyber Systems
  • Division of Materials Research
  • National Cancer Institute
  • Northwestern University
  • Office of Naval Research
  • Sherman Fairchild Foundation

Tags

Readers

  • Molecular Genetics
  • Nanocomposite Materials Science
  • Systems Analysis and Design

Technology Areas

  • Biotechnology
  • Space