Expeditious, scalable solution growth of metal oxide films by combustion blade coating for flexible electronics

Abstract

Solution-processing metal oxide (MO) films at low temperature enables their integration in mechanically flexible and inexpensive substrates for unconventional optoelectronics. However, temperature reduction has not been accompanied by a corresponding reduction in film-processing time, which remains far greater than acceptable for efficient/continuous additive manufacturing as in typical fabrication lines. Here, we report a highly efficient cofuel-assisted combustion process, which involves introducing both a fluorinated fuel and a preannealing step, that achieves ultrafast reaction and metal–oxygen–metal (M-O-M) lattice condensation within 10–60 s for several MO semiconductors and aluminum oxide dielectric. The resulting MO transistors exhibit high carrier mobility, excellent bias stability, and good flexibility.

Document Details

Document Type
Pub Defense Publication
Publication Date
Apr 19, 2019
Source ID
10.1073/pnas.1901492116

Entities

People

  • Antonio Facchetti
  • Aritra Sil
  • Binghao Wang
  • Gang Wang
  • Li Zeng
  • Matthew J. Leonardi
  • Michael Bedzyk
  • Peijun Guo
  • Richard D. Schaller
  • Shaofeng Lu
  • Tobin J. Marks
  • Wei Huang
  • Xinan Zhang
  • Yu Xia
  • Zhihua Chen

Organizations

  • Air Force Office of Scientific Research
  • Argonne National Laboratory
  • Henan University
  • National Science Foundation
  • Northwestern University
  • United States – Israel Binational Science Foundation

Tags

Fields of Study

  • Materials science

Readers

  • Polymer Science and Technology
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.
  • Systems Analysis and Design

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene