Spontaneous generation of hydrogen peroxide from aqueous microdroplets

Abstract

Water is considered to be a stable and relatively inert molecule in bulk solution. We report an exceptional behavior of water: Water molecules are spontaneously oxidized to form hydrogen peroxide near the water−air interface of micron-sized water droplets. This process does not require any chemical reagent, catalyst, applied electric potential, or radiation. Only pure water in the form of microdroplets in air is necessary for the appearance of hydrogen peroxide. We suggest that this discovery opens various innovative opportunities including green and inexpensive production of hydrogen peroxide, green chemical synthesis, safe cleaning, and food processing.

Document Details

Document Type
Pub Defense Publication
Publication Date
Aug 26, 2019
Source ID
10.1073/pnas.1911883116

Entities

People

  • Fritz B. Prinz
  • Hong Gil Nam
  • Hyun Soo Han
  • Jae Kyoo Lee
  • Jooyoun Kang
  • Katherine L Walker
  • Richard Zare
  • Robert Waymouth

Organizations

  • Air Force Office of Scientific Research
  • Daegu Gyeongbuk Institute of Science and Technology
  • Institute for Basic Science
  • Stanford University

Tags

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Gender and Food Studies
  • Systems Analysis and Design