Ferrous iron–activatable drug conjugate achieves potent MAPK blockade in KRAS-driven tumors

Abstract

KRAS mutations drive a quarter of cancer mortality, and most are undruggable. Several inhibitors of the MAPK pathway are FDA approved but poorly tolerated at the doses needed to adequately extinguish RAS/RAF/MAPK signaling in the tumor cell. We found that oncogenic KRAS signaling induced ferrous iron (Fe2+) accumulation early in and throughout mutant KRAS-mediated transformation. We converted an FDA-approved MEK inhibitor into a ferrous iron–activatable drug conjugate (FeADC) and achieved potent MAPK blockade in tumor cells while sparing normal tissues. This innovation allowed sustainable, effective treatment of tumor-bearing animals, with tumor-selective drug activation, producing superior systemic tolerability. Ferrous iron accumulation is an exploitable feature of KRAS transformation, and FeADCs hold promise for improving the treatment of KRAS-driven solid tumors.

Document Details

Document Type
Pub Defense Publication
Publication Date
Mar 09, 2022
Source ID
10.1084/jem.20210739

Entities

People

  • Adam Olshen
  • Adam R Renslo
  • Byron Hann
  • Eric Collisson
  • Honglin Jiang
  • Iwei Yeh
  • James E Korkola
  • Michael J Evans
  • Ning Zhao
  • Ryan K. Muir
  • Ryan L. Gonciarz
  • Spencer C Behr
  • Yung-hua Wang

Organizations

  • American Cancer Society
  • Congressionally Directed Medical Research Programs
  • National Institutes of Health
  • Oregon Health & Science University
  • University of California, San Francisco

Tags

Fields of Study

  • Biology

Readers

  • Materials Science and Engineering.
  • Oncology
  • Oncology (Cancer Research).