Systematic oxygen impurity reduction in smooth N-polar GaN by chemical potential control

Abstract

Process chemical potential control and dislocation reduction were implemented to control oxygen concentration in N-polar GaN layers grown on sapphire substrates via metal organic chemical vapor deposition (MOCVD). As process supersaturation was changed from ∼30 to 3400, the formation energy of the oxygen point defect increased, which resulted in a 25-fold decrease in oxygen incorporation. Reducing dislocations by approximately a factor of 4 (to ∼109 cm−3) allowed for further reduction of oxygen incorporation to the low-1017 cm−3 range. Smooth N-polar GaN layers with low oxygen content were achieved by a two-step process, whereas first a 1 µm thick smooth N-polar layer with high oxygen concentration was grown, followed by low oxygen concentration layer grown at high supersaturation.

Document Details

Document Type
Pub Defense Publication
Publication Date
Nov 29, 2021
Source ID
10.1088/1361-6641/ac3638

Entities

People

  • Dennis Szymanski
  • Felix Kaess
  • Ke Wang
  • Pramod Reddy
  • Ramón Collazo
  • Ronny Kirste
  • Seiji Mita
  • Zlatko Sitar

Organizations

  • National Science Foundation
  • United States Army Research Laboratory

Tags

Fields of Study

  • Materials science

Readers

  • Environmental Engineering
  • Semiconductor Device Technology