Synthesis and crystal structure of 2-[(2,3,5,6-tetrafluoropyridin-4-yl)amino]ethyl methacrylate

Abstract

In the title compound, C11H10F4N2O2, the conformation about the N—C—C—O bond is gauche [torsion angle = 61.84 (13)°]. In the crystal, N—H...O hydrogen bonds link the molecules into [010] chains, which are cross-linked by C—H...F and C—H...π contacts. Hirshfeld surface analysis was conducted to aid in the visualization of these various influences on the packing. This analysis showed that the largest contribution to the surface contacts arises from F...H/H...F interactions (35.6%), followed by O...H/H...O (17.8%) and H...H (12.7%).

Document Details

Document Type
Pub Defense Publication
Publication Date
May 26, 2023
Source ID
10.1107/s2056989023004334

Entities

People

  • Abby R Jennings
  • Alexander Nguyen
  • Andrew J Peloquin
  • Ian M. Genzia
  • Shayla M. J. Overstreet
  • Zachary J. Auleciems

Organizations

  • Air Force Office of Scientific Research
  • United States Air Force Academy

Tags

Fields of Study

  • Chemistry

Readers

  • Combustion and Flow Dynamics.
  • Materials Science and Engineering.
  • Polymer Science and Technology