9-(3,5-Dimethylbenzylidene)-8-(3,5-dimethylphenyl)-1,3,5,7-tetraphenyl-2,4,7,8-tetrahydro-4,7-methanoazulene acetonitrile disolvate

Abstract

The title Diels–Alder product, C52H44·2CH3CN, was obtained in trace quantity as the `endo' isomer during the synthesis of 1,3-diphenyl-6-(3,5-dimethylphenyl)fulvene. One of the two co-crystallized acetonitrile molecules is linked to the main molecule by a weak C—H...N hydrogen bond.

Document Details

Document Type
Pub Defense Publication
Publication Date
Apr 17, 2018
Source ID
10.1107/s2414314618005539

Entities

People

  • Andrew J Peloquin
  • Gary J Balaich
  • Scott T Iacono
  • Sonya K. Adas

Organizations

  • Air Force Office of Scientific Research
  • Defense Threat Reduction Agency

Tags

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Quantum Chemistry