(E)-1-[1-(3-Phenylcyclopenta-2,4-dien-1-ylidene)ethyl]pyrrolidine
Abstract
The title compound, C17H19N, is a disubstituted pentafulvene obtained from the hydroamination of 1-phenyl-3-trimethylsilylethynylcyclopentadiene and has monoclinic P21/n symmetry at 100 K. C—H...π ring interactions between neighboring molecules consolidate the packing. To the authors' knowledge, this reaction is the first reported example of a non-transition metal catalyzed hydroamination with concomitant desilylation.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jun 05, 2018
- Source ID
- 10.1107/s2414314618007642
Entities
People
- Andrew J Peloquin
- Gary J Balaich
- Madelyn B. Smith
- Scott T Iacono
Organizations
- Air Force Office of Scientific Research
- Defense Threat Reduction Agency