Densification and characterization of rapid carbothermal synthesized boron carbide

Abstract

Submicrometer boron carbide powders were synthesized using rapid carbothermal reduction (RCR) method. Synthesized boron carbide powders had smaller particle size, lower free carbon, and high density of twins compared to commercial samples. Powders were sintered using spark plasma sintering at different temperatures and dwell times to compare sintering behavior. Synthesized boron carbide powders reached >99% TD at lower temperature and shorter dwell times compared to commercial powders. Improved microhardness observed in the densified RCR samples was likely caused by the combination of higher purity, better stoichiometry control, finer grain size, and a higher density of twin boundaries.

Document Details

Document Type
Pub Defense Publication
Publication Date
Feb 13, 2017
Source ID
10.1111/ijac.12654

Entities

People

  • Kelvin Yu Xie
  • Kevin Jude Hemker
  • Luoning Ma
  • Muhammet Fatih Toksoy
  • Richard Alan Haber
  • William Rafaniello

Organizations

  • Defense Advanced Research Projects Agency
  • Johns Hopkins University
  • National Science Foundation
  • Rutgers University
  • United States Army Research Laboratory
  • İzmir Institute of Technology

Tags

Fields of Study

  • Materials science

Readers

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