Glass‐Like Thermal Conductivity of (010)‐Textured Lanthanum‐Doped Strontium Niobate Synthesized with Wet Chemical Deposition

Abstract

We have measured the cross‐plane thermal conductivity (κ) of (010)‐textured, undoped, and lanthanum‐doped strontium niobate (Sr2−xLaxNb2O7−δ) thin films via time‐domain thermoreflectance. The thin films were deposited on (001)‐oriented SrTiO3 substrates via the highly‐scalable technique of chemical solution deposition. We find that both film thickness and lanthanum doping have little effect on κ, suggesting that there is a more dominant phonon scattering mechanism present in the system; namely the weak interlayer‐bonding along the b‐axis in the Sr2Nb2O7 parent structure. Furthermore, we compare our experimental results with two variations of the minimum‐limit model for κ and discuss the nature of transport in material systems with weakly‐bonded layers. The low cross‐plane κ of these scalably‐fabricated films is comparable to that of similarly layered niobate structures grown epitaxially.

Document Details

Document Type
Pub Defense Publication
Publication Date
Nov 08, 2014
Source ID
10.1111/jace.13318

Entities

People

  • Brian M. Foley
  • Douglas L. Medlin
  • Harlan J. Brown‐shaklee
  • Jon F. Ihlefeld
  • Michael J. Campion
  • Patrick E Hopkins
  • Paul G. Clem

Organizations

  • Army Research Office
  • Sandia National Laboratories
  • United States Department of Commerce
  • United States Department of Energy
  • University of Virginia

Tags

Fields of Study

  • Materials science

Readers

  • Marine Hydrodynamics
  • Materials Science and Engineering.
  • Thin Film Deposition Science.