Heterogeneous domain configurations in ferroelectric crystals during thermal depolarization

Abstract

The phase transition and domain configurations in emerging ternary Mn‐doped Pb(In1/2Nb1/2)O3–Pb(Mg1/3Nb2/3)O3–PbTiO3 ferroelectric crystals have been investigated by high‐resolution X‐ray diffraction. Phase transition sequences of cubic→rhombohedral and monoclinic A→tetragonal→cubic were determined under zero‐field‐cooling and zero‐field‐heating after poling, respectively. Most importantly, a monoclinic‐like heterogeneous domain configuration was observed in the conventional high‐symmetry tetragonal phase field due to the coexistence of multiscale tetragonal variants. Our results provide further evidence that superlattices with low‐symmetry can be assisted by tetragonal nano‐twins.

Document Details

Document Type
Pub Defense Publication
Publication Date
Feb 14, 2017
Source ID
10.1111/jace.14746

Entities

People

  • D. Viehland
  • Guoliang Yuan
  • Haosu Luo
  • He Ma
  • Yaojin Wang

Organizations

  • Chinese Academy of Sciences
  • Nanjing University of Science and Technology
  • National Natural Science Foundation of China
  • Natural Science Foundation of Jiangsu Province
  • Office of Naval Research
  • Shanghai Institute of Ceramics
  • Virginia Tech

Tags

Readers

  • Distributed Systems and Data Platform Development
  • Materials Science and Engineering.