Kr ion irradiation study of polymer‐derived SiFeOC–C–SiC nanocomposite

Abstract

This study focuses on the pyrolysis and ion irradiation behaviors of polymer‐derived SiFeOC–C–SiC ceramic. The pyrolyzed material is composed of SiO2 and SiOC (amorphous), carbon (amorphous and turbostratic), and Fe3Si and β‐SiC (nanocrystalline). Irradiation was carried out at both room temperature and 600°C using 400 keV Kr ions with fluences of 4 × 1015 and 1 × 1016 ions cm−2, respectively. The Fe3Si and SiC nanocrystals are stable against irradiation up to 3 displacement per atom (dpa) at room temperature and up to 12 dpa at 600°C. The SiOC tetrahedrals show phase separation and minor carbothermal reduction. The high irradiation resistance and the dense, defect‐free amorphous microstructure of SiFeOC–C–SiC after prolonged irradiation demonstrate its great potential for advanced nuclear reactor applications.

Document Details

Document Type
Pub Defense Publication
Publication Date
May 29, 2022
Source ID
10.1111/jace.18572

Entities

People

  • Kathy Lu
  • Lin Shao
  • Sanjay Kumar Devendhar Singh

Organizations

  • Air Force Office of Scientific Research
  • Virginia Tech

Tags

Fields of Study

  • Materials science

Readers

  • Nuclear and Radiation Engineering.
  • Organic Chemistry
  • Thin Film Deposition Science.