Nanoscale etching of perovskite oxides for field effect transistor applications

Abstract

The etching of epitaxially grown perovskite oxide BaSnO3 (BSO) and BaTiO3 (BTO) thin films is studied using Cl-based (BCl3/Ar) and F-based (CF4/Ar) plasma chemistries in an inductively coupled plasma reactive ion etching (ICP-RIE) system for the development of field effect transistors (FETs). It is found that the BCl3/Ar process has a time-independent and a higher etch rate and creates a smooth etched surface, while the etch rate of BSO and BTO in CF4/Ar plasma decreases with the etching time duration. For the BCl3/Ar etching process, the etch rate increases with both ion density and ion energy, suggesting the combination of chemical plasma etching and physical ion sputtering mechanisms. Using the Cl-based etching process, BaSnO3 and BaTiO3 heterojunction FETs are developed. The devices with a gate length of 1.5 μm have a saturation current density of 287.6 mA/mm, a maximum transconductance of gm = 91.3 mS/mm, an FET mobility of 45.3 cm2/V s, and a threshold voltage of −1.75 V. The etching processes developed in this work will enable further development of perovskite oxide heterostructure electronic devices.

Document Details

Document Type
Pub Defense Publication
Publication Date
Dec 18, 2019
Source ID
10.1116/1.5122667

Entities

People

  • Caiyu Wang
  • Christopher R. Freeze
  • Hao Yang
  • Hareesh Chandrasekar
  • Junao Cheng
  • Nick Combs
  • Nidhin Kurian Kalarickal
  • Omor Shoron
  • Siddharth Rajan
  • Susanne Stemmer
  • Wangzhou Wu
  • Wu Lu

Organizations

  • Defense Advanced Research Projects Agency
  • Ohio State University
  • University of California, Santa Barbara

Tags

Fields of Study

  • Materials science

Readers

  • Nanofabrication and Microfabrication.
  • Solar Photovoltaics and Thermoelectric Devices.
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene