Molecular beam homoepitaxy of N-polar AlN: Enabling role of aluminum-assisted surface cleaning

Abstract

N-polar aluminum nitride (AlN) is an important building block for next-generation high-power radio frequency electronics. We report successful homoepitaxial growth of N-polar AlN by molecular beam epitaxy (MBE) on large-area, cost-effective N-polar AlN templates. Direct growth without any in situ surface cleaning leads to films with inverted Al polarity. It is found that Al-assisted cleaning before growth enables the epitaxial film to maintain N-polarity. The grown N-polar AlN epilayer with its smooth, pit-free surface duplicates the structural quality of the substrate, as evidenced by a clean and smooth growth interface with no noticeable extended defects generation. Near band-edge photoluminescence peaks are observed at room temperature on samples with MBE-grown layers but not on the bare AlN templates, implying the suppression of nonradiative recombination centers in the epitaxial N-polar AlN.

Document Details

Document Type
Pub Defense Publication
Publication Date
Sep 09, 2022
Source ID
10.1126/sciadv.abo6408

Entities

People

  • Akira Sakai
  • Debdeep Jena
  • Hideto Miyake
  • Huili Grace Xing
  • Jashan Singhal
  • Tetsuya Tohei
  • Vladimir Protasenko
  • Yong-Jin Cho
  • Yusuke Hayashi
  • Zexuan Zhang

Organizations

  • Cornell University
  • Mie University
  • Osaka University

Tags

Fields of Study

  • Materials science

Readers

  • Semiconductor Device Technology

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene