Unimpeded Permeation of Water Through Helium-Leak–Tight Graphene-Based Membranes
Abstract
Thin semi-permeable membranes are commonly used as chemical barriers or for filtration purposes. While the size of the pores will influence which molecules are able to pass, other factors—including the surface chemistry of the pore walls, electrostatic interactions, and differences in solubility—can also affect the diffusion rates. There is also a trade-off between the thickness of the membrane regarding strength and permeation rates (see the Perspective by Paul ). Karan et al. (p. 444 ) fabricated membranes from amorphous carbon, which showed excellent strength and could be used for filtrations involving organic solvents. Nair et al. (p. 442 ) observed unusual behavior in graphene-based membranes which were able to prevent the diffusion of many small-molecule gases, including helium, but showed almost barrier-free movement of water.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 27, 2012
- Source ID
- 10.1126/science.1211694
Entities
People
- Andre Geim
- H. A. Wu
- I. V. Grigorieva
- P. N. Jayaram
- R. R. Nair
Organizations
- Air Force Office of Scientific Research
- Chinese Academy of Sciences
- Office of Naval Research
- University of Manchester