Structural Stereochemistry of Androstene Hormones Determines Interactions with Human Androgen, Estrogen, and Glucocorticoid Receptors

Abstract

DHEA, 17α-AED, 17β-AED, and 17β-AET exhibit strong biological activity that has been attributed to androgenic, estrogenic, or antiglucocorticoid activity in vivo and in vitro. This study compared DHEA, 17α-AED, 17β-AED, and 17β-AET for their ability to activate the human AR, ER, and GR and determine the relative androgenicity, estrogenicity, and glucocorticoid activity. The results show that, at the receptor level, these androstene hormones are weak AR and even weaker ER activators. Direct androstene hormone activation of the human AR, ERα, and ERβmay not be essential for their biological function. Similarly, these hormones indirectly activated the human GR, only in the presence of high dexamethasone concentrations. These results underscore the major difference between androstene hormone interactions with these nuclear receptors and their biological effects.

Document Details

Document Type
Pub Defense Publication
Publication Date
Apr 04, 2013
Source ID
10.1155/2013/203606

Entities

People

  • Charles E. Chalfant
  • Dayanjan S. Wijesinghe
  • Kevin R. Ward
  • Robert F. Diegelmann
  • Roger M. Loria
  • Thomas L. Shaak

Organizations

  • Hunter Holmes McGuire Veterans Administration Medical Center
  • United States Army Medical Research and Development Command
  • University of Michigan
  • Virginia Commonwealth University

Tags

Fields of Study

  • Chemistry

Readers

  • Prostate Cancer Biology.