Mechanical response of carbon nanotube reinforced particulate composites with implications for polymer bonded explosives

Abstract

Modern polymer bonded explosives (PBX) are often characterized by a sensitive response to external thermomechanical insult that in some cases lead to accidental detonation. Current strategies for desensitizing PBXs come at the expense of a significant reduction in performance. A possible method for desensitizing PBX without adverse performance effects is the multifunctional tailoring of mechanical properties through strategic incorporation of multi-walled carbon nanotubes (MWCNTs) directly into the binder phase. In this work, a fabrication method is presented that produces polymer bonded simulants (PBS) of PBX that incorporate MWCNTs into the binder phase, hydroxyl-terminated polybutadiene (HTPB). These materials were characterized via microscopy and unconfined quasi-static compression testing to determine the effects of MWCNTs. Quasi-static compression showed evidence of a MWCNT induced structural skeleton effect that provided the binder with an increased strength, load transfer, and a greater ability to resist strain localizations prior to failure. These enhancements demonstrate the potential of using MWCNTs to enhance energetic materials.

Document Details

Document Type
Pub Defense Publication
Publication Date
Feb 04, 2021
Source ID
10.1177/0021998321990863

Entities

People

  • Eliseo E. Iglesias
  • Justin Wilkerson
  • Kyle Fernandez
  • Sidney Chocron
  • Tyler Rowe

Organizations

  • Air Force Office of Scientific Research
  • Southwest Research Institute
  • Texas A&M University
  • University of Texas at San Antonio

Tags

Fields of Study

  • Materials science

Readers

  • Neurological Diseases/Conditions/Disorders
  • Reinforced Composite Materials
  • Rocket Propulsion.