Resolved rotation–vibration non-equilibrium with rotational VIPA-CARS

Abstract

Simultaneous rotational and vibrational temperatures are measured in an N2 plasma with rotational coherent anti-Stokes Raman scattering (CARS) resolved with a virtually imaged phased array (VIPA)-based spectrometer. A VIPA spectrally separates rotational transitions for each vibrational state, allowing vibrational populations to be directly measured. VIPA-CARS is shown to provide more accurate measurements of non-equilibrium temperatures than grating-resolved rotational CARS. The general characteristics, limitations, and potential uses of VIPA-CARS are discussed.

Document Details

Document Type
Pub Defense Publication
Publication Date
Oct 14, 2022
Source ID
10.1364/ol.474037

Entities

People

  • Benjamin M. Goldberg
  • Christopher J Kliewer
  • Christopher Limbach
  • Scott Steinmetz
  • Timothy Y. Chen

Organizations

  • Army Research Office
  • Lawrence Livermore National Laboratory
  • National Nuclear Security Administration
  • Office of Science
  • Sandia National Laboratories California
  • Texas A&M University

Tags

Fields of Study

  • Physics

Readers

  • Molecular Photonics/Laser Physics