Growth of Pseudomorphic GeSn at Low Pressure with Sn Composition of 16.7%

Abstract

Group-IV alloy GeSn holds great promise for the high-performance optoelectronic devices that can be monolithically integrated on Si for near- and mid-infrared applications. Growth of GeSn using chemical vapor deposition technique with various Sn and Ge precursors has been investigated worldwide. To achieve relatively high Sn incorporation, the use of higher pressure and/or higher order Ge hydrides precursors were reported. In this work, we successfully demonstrated the growth of high-quality GeSn with Sn composition of 16.7% at low pressure of 12 Torr. The alloy was grown using the commercially available GeH4 and SnCl4 precursors via a chemical vapor deposition reactor. Material and optical characterizations were performed to confirm the Sn incorporation and to study the optical properties. The demonstrated growth results reveal a low-pressure growth window to achieve high-quality and high Sn alloys for future device applications.

Document Details

Document Type
Pub Defense Publication
Publication Date
Dec 11, 2021
Source ID
10.3390/ma14247637

Entities

People

  • Abbas Sabbar
  • Bao-hua Li
  • Emmanuel Wanglia
  • Grey Abernathy
  • Joshua M. Grant
  • Murtadha Alher
  • Oluwatobi Olorunsola
  • Samir K. Saha
  • Shui-Qing Yu
  • Solomon Ojo
  • Sylvester Amoah
  • Wei Du

Organizations

  • Air Force Office of Scientific Research

Tags

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.
  • Semiconductor Device Technology

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene