Conformer-Specific Dissociation Dynamics in Dimethyl Methylphosphonate Radical Cation
Abstract
The dynamics of the dimethyl methylphosphonate (DMMP) radical cation after production by strong field adiabatic ionization have been investigated. Pump-probe experiments using strong field 1300 nm pulses to adiabatically ionize DMMP and a 800 nm non-ionizing probe induce coherent oscillations of the parent ion yield with a period of about 45 fs. The yields of two fragments, PO2C2H7+ and PO2CH4+, oscillate approximately out of phase with the parent ion, but with a slight phase shift relative to each other. We use electronic structure theory and nonadiabatic surface hopping dynamics to understand the underlying dynamics. The results show that while the cation oscillates on the ground state along the P=O bond stretch coordinate, the probe excites population to higher electronic states that can lead to fragments PO2C2H7+ and PO2CH4+. The computational results combined with the experimental observations indicate that the two conformers of DMMP that are populated under experimental conditions exhibit different dynamics after being excited to the higher electronic states of the cation leading to different dissociation products. These results highlight the potential usefulness of these pump-probe measurements as a tool to study conformer-specific dynamics in molecules of biological interest.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Mar 31, 2022
- Source ID
- 10.3390/molecules27072269
Entities
People
- Hugo A. López Peña
- Jacob M. Shusterman
- Katharine Moore Tibbetts
- Patricia Vindel-Zandbergen
- Spiridoula Matsika
- Vaibhav Singh
Organizations
- Army Research Office
- National Science Foundation
- United States Department of Energy