POLYNUCLEAR AROMATIC COMPOUNDS FOR HIGH TEMPERATURE LUBRICANTS

Abstract

A literature survey was made of low mol wt aromatic compounds which are liquid at 95 deg F, stable up to 400 deg F, and contain 2 or 3 nuclear rings. A list of 17 compounds considered to be representative of common chemical structures was compiled from the data. These compounds were evaluated as to thermal stability, viscosity at 100 deg and 210 deg F, density, and 6p. The results indicated that the aryl phosphates generally provide compounds with the desired properties. Investigation into the aryl phosphate field yielded 3 liquid compounds with thermal stabilities above 700 deg F: (1) di-p-tolyl 1-naphtyl phosphate, (2) di-m-tolyl 1-naphthyl phosphate, and (3) tri-o-chlorophenyl phosphate. The first 2 compounds gave good results for flash and fire points, autogenous ignition temperature, and hydrolytic stability. The chemical syntheses are discussed as well as the procedure for the literature survey.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1953
Accession Number
AD0018896

Entities

People

  • Charles F. Raley Jr

Organizations

  • Southwest Research Institute

Tags

Communities of Interest

  • Air Platforms
  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Air Force
  • Aromatic Compounds
  • Barometric Pressure
  • Boiling Point
  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Literature Surveys
  • Materials
  • Materials Laboratories
  • Organic Chemistry
  • Thermal Stability

Readers

  • Organic Chemistry
  • Petroleum Engineering