RESEARCH ON BORON POLYMERS
Abstract
A new, simple, and efficient synthesis of boron substituted borazoles has been developed. Butylboron dichloride reacts with aminonia to give a high yield of B-tributylborazole. This synthesis will be broadened by the employment of substituted arnines. Some of the resulting B-N substituted borazoles may serve as the basis of thermally and hydrolytically stable semi-inorganic polymers and the liquid borazoles will be evaluate as nbricants and bydraulic fluids. The preparation of benzeneboronic acid, tri-n-butylborine, butylboron dichloride and phenylboron dichioride as interniediates for our new borazole synthesis has been studied. A new catalytic recirculating apparatus for preparin% phenylboron dichloride from benzene and boron trichloride by Pace's method is described.
Document Details
- Document Type
- Technical Report
- Publication Date
- May 01, 1956
- Accession Number
- AD0100806
Entities
People
- Frank C. Gunderloy Jr.
- Michael Sedlak
- P. A. Van Der Meulen
- William L. Ruigh
Organizations
- Rutgers University–New Brunswick