The Donor Properties of Pyridine-N Oxide
Abstract
The coordination chemistry of pyridine N-oxide with a variety of acceptors has been investigated. The new substances Co(ClO4)2.6L, Co(NO3)2.6L, CoCl2.3L, CoCl2.L.H20, Ni(ClO4)2.6L, NiCl2.L.H2O, NiBr2.6L, NiI2.6L, NiBr2.L. H2O, Cu(ClO4)2.4L, Cu(NO3)2.2L, CuCl2.L, CuCl2.2L, Zn(ClO4)2.6L, ZnCl2.2L, Zn(NO3)2.6L, Fe(ClO4)2.6L, Fe(ClO4)3.6L, and SnBr4.2L (where L is pyridine N-oxide) have been isolated and characterized by molecular conductance measurements in non-aqueous solvents, magnetic susceptibility measurements, and infrared spectra. All of the perchlorates and some of the nitrates and halides have only the pyridine N-oxide in the first coordination sphere. However, in some cases, both nitrates and halides are coordinated to the central ion.
Document Details
- Document Type
- Technical Report
- Publication Date
- Feb 01, 1961
- Accession Number
- AD0250779
Entities
People
- D. J. Phillips
- G. Franz
- J. A. Walmsley
- J. Fujita
- J. V. Quagliano
- S. Y. Tyree
Organizations
- University of North Carolina at Chapel Hill