ATOMIC ARRANGEMENTS IN TITANIUM-MOLYBDENUM SOLID SOLUTIONS

Abstract

The short range order and size effect coefficients as well as the thermal and static atomic displacements have been measured in bcc solid solutions of Ti-Mo using X-ray diffraction techniques. These solutions exhibit a strong preference for unlike near-neighbors even though a superlattice was not found. The size effect coefficients for the first shell of atoms were negative, indicating that the Mo atoms were smaller than the Ti atoms in solution. Centerto-center distances between the different pairs of nearest neighbor atoms were calculated from the size effect coefficients and the lattice parameters. Ti-Ti and Mo-Mo distances tended to approach the average distance in the solution at compositions between 20 and 50 at-% Mo. At 75% Mo the Mo-Mo distance was smaller than in pure Mo and this was taken to indicate an electron exchange in the solution. (Author)

Document Details

Document Type
Technical Report
Publication Date
Dec 27, 1960
Accession Number
AD0253154

Entities

People

  • B.l. Averbach
  • J.m. Dupouy

Organizations

  • Massachusetts Institute of Technology

Tags

DTIC Thesaurus Topics

  • Alloys
  • Chemistry
  • Coefficients
  • Crystal Lattices
  • Crystal Structure
  • Diffraction
  • Metallurgy
  • Physical Metallurgy
  • Solid Solutions
  • Titanium
  • Titanium Alloys
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Powder metallurgy of Titanium alloys.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene