PREDISSOCIATION BY ROTATION OF THE OH MOLECULE

Abstract

The rotational analysis of the B 2 - A 2 system of the OH molecule shows a predissociation of the upper B 2 state in one normal hydrogen atom and one excited O(1S) atom. The effective potential curves for this state are calculated and allow to check the predissociation assumption. The O(1S) atoms give in the OH and OD spectra small continuous quasi-molecular spectra. Moreover, in the OH spectrum one observes near the (OI) 5577 line, a set of isolated lines also ascribed to complex molecules. The rotational structure of the above system for the OD molecule is given in tables. Complementary experimental data are given for the C 2 - A 2 system of OH. (Author)

Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1961
Accession Number
AD0256951

Entities

People

  • L. Herman

Organizations

  • Paris Observatory, PSL University

Tags

DTIC Thesaurus Topics

  • Experimental Data
  • Hydrogen
  • Molecules
  • Rotation
  • Spectra

Fields of Study

  • Physics

Readers

  • Molecular Photonics/Laser Physics
  • Statistical inference.