THE MECHANISM OF OXIDE FORMATION IN THE INITIAL STAGES OF OXIDATION

Abstract

Research was conducted on the mechanism of oxide formation by means of a field emission microscope with a tungsten emission tip. Changes in the emission were observed as a result of adsorption of residual gases on the emission tip at room temperature. An improvement was made in the technique for producing field emission tubes by the development of a refractory masking material for pyrex. The high-vacuum technique was refined by the addition of a second getter to the system and the use of a H-purge at elevated temperatures to decontaminate the isolation trap. As adsorption increased the following changes were observed in emission pattern: (1) a gradual decrease followed by an increase in total integrated emission intensity; (2) a gradual decrease followed by an increase in local emission intensity of the area around (111) regions bounded by (211) regions; (3) an initial increase followed by a decrease in the size of the lowintensity regions around (110) and (211); and (4) an initial decrease followed by an increase in the size of the low intensity regions around (100).

Document Details

Document Type
Technical Report
Publication Date
Apr 14, 1961
Accession Number
AD0257035

Entities

People

  • D.w. Rausch
  • K.l. Moazed
  • M.g. Fontana

Organizations

  • Ohio State University

Tags

DTIC Thesaurus Topics

  • Adsorption
  • Emission
  • Field Emission
  • Field Emission Tubes
  • High Vacuum
  • Intensity
  • Materials
  • Microscopes
  • Oxidation
  • Oxides
  • Residuals
  • Tungsten
  • Vacuum

Readers

  • Pulsed Power and Plasma Physics.
  • Spectroscopy.
  • Surface Engineering/Surface Coating Technology.