STUDY OF THE ADDITION REACTION BETWEEN TRIALKOXYSILANES AND OLEFINS
Abstract
The addition of trialkoxysilanes to olefins was demonstrated by interacting triethoxysilane, triisopropoxysilane, tributoxysilane, tri(sec-butoxy)-silane, and tri(tert-butoxy)silane with 1-nonene and 1-decene in the presence of chloroplatinic acid and platinized charcoal. In the presence of chloroplatinic acid a yield of 30 to 40% was obtained. The addition of tri(tert-butoxy)silane, due to steric hindrance, gave the lowest yields of all (12%). Decyltributoxysilane and nonyltriisopropoxysilane were also obtained by direct synthesis, by the reaction of nonyltrichlorosilane and decyltrichlorosilane with the corresponding alcohols. The physicochemical properties of the alkyl-trialkoxysilanes obtained by both methods, addition to olefins and reaction with alcohols, were identical.
Document Details
- Document Type
- Technical Report
- Publication Date
- Oct 01, 1960
- Accession Number
- AD0257140
Entities
People
- A.v. Topchiyev
- N.s. Nametkin
Organizations
- National Air and Space Intelligence Center