Some Luminescant Properties of the Mixed Phenyl- and p-Biphenylyl-Substituted Silanes under Ultra-Violet, Gamma and Beta Excitation

Abstract

Luminescent properties of triphenyl-p-biphenylylsilane (silane I), biphenyl-di-p-biphenylylsilane (silane II) and phenyl-tri-p-biphenylylsilane (silane III) have been investigated. In comparing these phosphors with anthracene the following results were obtained: (a) Silane I is 8% less effective than anthracene in its gamma detecting ability. (b) The pulse height of the silanes is about 40% - 45% that of anthracene. (c) Each of the silanes is about 70% as efficient a beta detector as anthracene. Fluorescence spectra for each of the silanes under ultraviolet and beta stimulation are reported. Peak emission wave-lengths are 400, 400, and 450 millimicrons for Silane I, II, and III respectively. Fluorescence decay constants of 2.53-2.54, 2.62-2.63 and 3.29-3.31 nanoseconds were found for Silane I, II, and III.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1961
Accession Number
AD0259662

Entities

People

  • Carl G. Weis

Organizations

  • Air Force Institute of Technology

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force
  • Chemical Synthesis
  • Chemistry
  • Detection
  • Detectors
  • Energy
  • Energy Levels
  • Geometry
  • Ionizing Radiation
  • Luminescence
  • Materials
  • Measurement
  • Melting Point
  • New York
  • Organic Materials
  • Photomultiplier Tubes
  • Quantum Efficiency
  • Scintillation
  • Scintillation Counters
  • Silicon Compounds
  • Solid State Physics

Readers

  • Chemistry (specifically Chemical Fluorescence)
  • Organic Chemistry
  • Solar Physics