Studies of Light Weight Elements
Abstract
Results are given to show that a volatile Si-N compound, (SiH3NSiH2)3, other than trisilylamine can be isolated from the reaction of silyl chloride and NH3. The compound is thought to be N, N', N'' -trisilylcyclotrisilazane. The proton nuclear magnetic resonance spectra of C2H5I, CH3SiH3, and CH3SiH2I were obtained in CS2 solution with tetramethylsilane added as an internal standard. That of Si2H5I, disilanyl iodide, was observed in the neat state and with Me4Si and as a solution with CC14. Exchange reactions were observed between trisilylamine and trisilylamine-d sub 9 and trisilylamine and silyl chloride-d sub 3. The reaction of (SiH3)3N and DC1 did not indicate that any H exchange occurred during the reaction. Reactions of nickel carbonyl with biphosphines and of PF3 with Ni(CO)4 were also studied.
Document Details
- Document Type
- Technical Report
- Publication Date
- Aug 31, 1961
- Accession Number
- AD0263749
Entities
People
- Louis Ross
- Martin Thompson
- Richard Wells
- Riley Schaeffer
Organizations
- Indiana University