DETERMINATION OF OXAMIDE IN NITROCELLULOSE-BASE PROPELLANTS

Abstract

A rapid and accurate method for the determination of oxamide in propellants is proposed. The meth d is based on the hydrolysis of oxamide in alkaline medium, yielding oxalic acid and ammonia. The propellant, after preliminary solvent extraction, is steam distilled fro a ten per cent aqueous sodium hydroxide solution. The liberated ammonia is trapped in a receiver containing an excess of standard hydrochloric acid. The excess acid is then bac titrated with standard alkali and the oxamide calculated on the basis that one mole of oxamide yields two moles of ammonia. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1961
Accession Number
AD0264110

Entities

People

  • Joseph Cohen
  • Julius B. Apatoff

Organizations

  • Frankford Arsenal

Tags

DTIC Thesaurus Topics

  • Acids
  • Chemical Compounds
  • Extraction
  • Hydrochloric Acid
  • Hydrolysis
  • Hydroxides
  • Nitrocellulose
  • Oxalic Acid
  • Propellants
  • Sodium
  • Sodium Hydroxide
  • Solvent Extraction
  • Standards

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Organic Chemistry
  • Rocket Propulsion.