ELECTROCHEMICAL BEHAVIOUR OF OXYGEN AND HYDROGEN PEROXIDE ON ALUMINUM, TANTALUM AND ZIRCONIUM ELECTRODES

Abstract

The cathodic reduction of O and H2O2 on Al, Ta, and Zr was studied by means of a polarization cell and an electronic potentiostat. Al, Ta and Zr, although covered by an oxide layer, actedAS CATHODE FOR THE PROCESSES OF O and H2O2 reduction. Overvoltage valves and the polarization curves are listed. The results obtained on these 3 metals are compared with those previously obtained on Ti. Overvoltages for cathodic reduction of O decrease in the following order: Zr, Ta, Ti for acid; Al, Ta, Zr, Ti for neutral; and Zr, Ti, Ta for alkaline solutions. These results indicate that the dangers of galvanic corrosion with Zr and Ta are less than those for Ti.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1960
Accession Number
AD0264718

Entities

People

  • G. Bianchi
  • G. Caprioglio

Organizations

  • University of Milan

Tags

DTIC Thesaurus Topics

  • Acids
  • Air Force
  • Anodic Polarization
  • Corrosion
  • Current Density
  • Depolarization
  • Films
  • Galvanic Corrosion
  • Government Procurement
  • Heat Treatment
  • High Temperature
  • Metals
  • Oxide Films
  • Oxides
  • Plastic Explosives
  • Polarization
  • Rocket Oxidizers

Fields of Study

  • Materials science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Materials Science and Engineering.
  • Surface Engineering/Surface Coating Technology.

Technology Areas

  • Microelectronics