High Resolution Nuclear Magnetic Resonance Spectra of the Pentafluorosulfur Group (TR-31) and Nuclear Magnetic Resonance Spectra of Some Hypofluorites (TR-32)
Abstract
This report includes: HIGH RESOLUTION NUCLEAR MAGNETIC RESONANCE SPECTRA OF THE PENTAFLUOROSULFUR GROUP, by C. I. Merrill, S. M. Williamson and others. 1961. (Technical rept. no. 31) (Contract Nonr-47716). High resolution NMR spectra were obtained for substances containing the -SF5 group. Complex spin-spin interaction effects were observed over a large range of J/delta values. A graphical method is presented of estimating the values of delta, J/ delta, and line positions in the spectra of AB4 NMR systems having J/delta values in the range of 0.15 to 0.7. NUCLEAR MAGNETIC RESONANCE SPECTRA OF SOME HYPOFLUORITES, by Claude I. Merrill and George H. Cady. 1961. (Technical rept. no. 32) (Contract Nonr-47716) The NMR spectra of F2, OF2, SF5OF, SO3F2, and CF3OF were observed at room temperature with SF6 as an internal reference. F absorbs at lowest magnetic field strength while with increasing field absorption due to the hypofluorite F atoms fall in the order given above. Only the NMR spectrum of SF3OF exhibited observable second order spin-spin spectrum.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 01, 1961
- Accession Number
- AD0264827
Entities
Organizations
- University of Washington