ACCELERATED DETERIORATION OF TEXTILES

Abstract

Reasons for the difference in photooxidative degradation between cellophane and cotton were investigated. Uranyl oxalate actinometers were used to measure quantitatively the amounts of light transmitted and reflected by the cellophane and cotton. Cellophane containing 0.2% ferric ion, absorbed about 5% of the light. Cotton fabric containing 0.2% ferric ion absorbed more light than the cellophane, but no accurate measurements could be made. Tests were conducted on the acceleration of degradation by heat absorption in cotton and cellophane samples impregnated to equal contents of ferric ion. Tests were on the following degradation accelerators; ferrocene (dicyclopentadienyl iron), dicyclopentadienyl titanium dichloride, ceric ion, and cerous ion. In the limited experiments to date it has been found that cerium, applied to cotton either as cerous ion or as ceric ion, does promote photodegradation.

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Document Details

Document Type
Technical Report
Publication Date
Oct 16, 1961
Accession Number
AD0264930

Entities

People

  • Anthony M. Schwartz
  • Charles A. Rader

Tags

DTIC Thesaurus Topics

  • Air Temperature
  • Catalysts
  • Cellophane
  • Cellulose
  • Chemical Reactions
  • Contracts
  • Degradation
  • Ferrocenes
  • Government Procurement
  • Governments
  • Intensity
  • Materials
  • Measurement
  • Quantum Yields
  • Reflectance
  • Time Intervals
  • Titanium

Readers

  • Battery Technology and Engineering
  • Materials Science and Engineering.
  • Organic Chemistry