THE THERMODYNAMIC PROPERTIES OF NITROTRICHLOROMETHANE

Abstract

From measurements of its vibrational spectrum and electron diffraction, the heat capacity, enthalpy, free energy and entropy of nitrotrichloromethane as an ideal gas have been calculated at a pressure of one atm. and for one hundred degree intervals over the range 200 to 700 K. The calculation was based on a rigid rotator, simple harmonic oscillator model. Motion of the symmetric top about the carbon nitrogen axis adds a free internal rotation contribution to the thermodynamic properties. (Author)

Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1961
Accession Number
AD0265528

Entities

People

  • Alexander H. Castelli
  • Frank Pristera

Organizations

  • Picatinny Arsenal

Tags

DTIC Thesaurus Topics

  • Diffraction
  • Electron Diffraction
  • Enthalpy
  • Free Energy
  • Heat Capacity
  • Measurement
  • Spectra
  • Thermodynamic Properties
  • Vibrational Spectra

Fields of Study

  • Chemistry

Readers

  • Combustion science or combustion engineering.
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.

Technology Areas

  • Microelectronics