PREPARATION OF DEUTERATED COLEMANITE

Abstract

The preparation of deuterated colemanite was undertaken to provide sufficient material to allow a comparison of its ferroelectric properties with that of naturally occurring mineral colemanite and also with synthetic normal colemanite. The reactants, deuterated Borax (Na2B4O7.10D2O) and Meyerhofferite (2CaO.3B407. 7D2O) were prepared. Two reactions were performed to produce the colemanite. In the first reaction the Meyerhofferite and Borax were reacted with D2O and normal colemanite seeds at 68 Cfor 56 days. Conversion to deuterated colemanite was complete. The second reaction was modified slightly by using fewer grams of the reactants in the same ratio as in the first reaction. After 88 days at 68C only about 50% conversion occurred.

Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1961
Accession Number
AD0267654

Entities

People

  • Charles R. Parkerson

Organizations

  • Naval Ordnance Laboratory

Tags

DTIC Thesaurus Topics

  • Conversion

Readers

  • Combustion science or combustion engineering.
  • Immunology
  • Materials Science and Engineering.