ON MOLECULAR VIBRATIONAL RELAXATION IN THE FLOW OF A CHEMICALLY REACTING GAS

Abstract

A method is presented for predicting the molecular vibrational temperature in a gas flow where the internal energy of vibration is small compared to the total internal energy of the gas. Coupling between the relaxation rate of molecular vibration and atomic recombination is neglected. The results of calculations suggest that large differences between the vibrational temperature and the random translational temperature of an oxygen-like gas can occur in certain flow configurations such as the flow of a chemically reacting gas through a hypersonic nozzle. A criterion is proposed which determines the position in the flow at which significant departures from vibrational equilibrium are likely to occur. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1961
Accession Number
AD0267761

Entities

People

  • J.p. Appleton
  • P.j. Musgrove

Organizations

  • University of Southampton

Tags

DTIC Thesaurus Topics

  • Couplings
  • Flow
  • Gas Flow
  • Hypersonic Nozzles
  • Lepidoptera
  • Nozzles
  • Vibration
  • Vibrational Relaxation

Fields of Study

  • Physics

Readers

  • Combustion science or combustion engineering.
  • Fluid Dynamics.
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.

Technology Areas

  • Hypersonics
  • Hypersonics - Hypersonic Flight
  • Hypersonics - Hypersonic Flow