Preparation of the Fluorosulfonates: KI(SO3F)4, KBR(SO3F)4, SNCL(SO3F)3, AND CRO2(SO3F)2

Abstract

It is known that peroxydisulfuryl difluoride, S2O6F2, reacts with some chlorides to replace chlorine by the fluorosulfonate group. This type of reaction has now been used to prepare SnCl(SO3F)3 from SNCL4 and CrO2(SO3F)2 from CrO2Cl2. It has also been shown that S2O6F2 fails to replace the halogen in KBr or KI when reacting at about room temperature. Instead of this the complex salts, KBr(SO3F)4 and KI(SO3F)4, are formed.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1961
Accession Number
AD0269138

Entities

People

  • George Hamilton Cady
  • Max Lustig

Organizations

  • University of Washington

Tags

DTIC Thesaurus Topics

  • Barium Compounds
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Chlorine
  • Dielectric Gases
  • Fluorides
  • Government Procurement
  • Halogens
  • Hydrolysis
  • Hydroxides
  • Infrared Spectra
  • Materials
  • Potassium
  • Sodium Hydroxide
  • United States
  • Vacuum Distillation

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  • Organic Chemistry