STUDY LEADING TO THE DEVELOPMENT OF HIGH TEMPERATURE RESISTANT ADHESIVES

Abstract

CHEMICAL MODIFICATIONS WERE ATTEMPTED ON POLY2,6-XYLENOLS AND CONDENSATION TRIAZINE TYPE POLYMERS WHICH HAD BEEN FOUND TO BE SUITABLE BASE MATERIAL FOR HIGH TEMPERATURE ADHESIVES FOR SAINLESS STEEL. Poly-2,6xylenol was prepared. High molecular weight polyxylenols had goodADHESION (2000-3000 psi) t room temperature, but lost srength to 10% of the original after heating at 550 F. for 30 min. The low molecular weight material may flow better and therefore impart better wetting. Several low molecular weight polyxylenols were prepared. 2-Methyl-6allyl-4-bromophenol was prepared and a polymer was prepared from it by the Price method of oxidative couphing. Nitration of 2,4,6-triphenyls-triazine yields 2,4-(di-(m-nitrophenyl)-6phenyl-s-triazine. Reduction of this derivative gives the diamino compound. (Author)

Document Details

Document Type
Technical Report
Publication Date
Sep 30, 1961
Accession Number
AD0269833

Entities

People

  • B.d. Halpern
  • J. Dickstein
  • K.c. Tsou

Tags

DTIC Thesaurus Topics

  • Adhesives
  • Condensation
  • High Temperature
  • Materials
  • Molecular Weight
  • Nitration
  • Reinforcing Materials
  • Transition Temperature
  • Triazines

Fields of Study

  • Chemistry

Readers

  • Mathematics or Statistics
  • Organic Chemistry
  • Polymer Science and Technology