CHEMICAL DETONATIONS IN THE UPPER ATMOSPHERE

Abstract

Detonation characteristics of hydrogen-air mixtures in the 1959 ARDC Model Atmosphere environment, including atomic oxygen and nitrogen, are computed to 450,000 ft assuming one-dimensional, inviscid, real-gas conditions. The velocity limits of strong detonations (based on total enthalpy change) are discussed. Atomic oxygen reactant suppresses the exothermic reaction to H2O in favor of recombination, making hydrogen use above 400,000 ft unattractive. Equilibrium temperature and pressure ratios across detonations decrease with altitude, especially above 350,000 ft; they are extremely sensitive, and inversely proportional, to reactant temperature, and pressure exhibits a secondary effect. For comparable detonation conditions, acetylene appears almost as good an energy source as hydrogen. (Author)

Document Details

Document Type
Technical Report
Publication Date
Oct 20, 1961
Accession Number
AD0270927

Entities

People

  • Doug Wilson
  • K.m. Foreman

Tags

DTIC Thesaurus Topics

  • Acetylenes
  • Alkynes
  • Altitude
  • Atmospheres
  • Detonations
  • Enthalpy
  • Enthalpy Changes
  • Environment
  • Exothermic Reactions
  • Hydrogen
  • Nitrogen

Readers

  • Combustion science or combustion engineering.
  • Fluid Dynamics.