COCRYSTALLIZATION OF ULTRAMICRO QUANTITIES OF IRON AND OTHER ELEMENTS WITH OXINE GENERATED IN SITU

Abstract

The cocrystallization of Fe in trace quantities with oxine formed homogeneously in solution by the hydrolysis of 8-acetoxyquinoline was studied. The distribution of microcomponent between the solid phase and the mother liquor was profoundly affected by the degree of supersaturation. After relief from supersaturation, a constant distribution coefficient was calculated by an equation which was predicated upon the Doerner-Hoskins equilibrium. The cocrystallization of other elements was also examined with an arbitrarily established set of conditions. Pu, Ce, and Pr were quantitatively recovered from solution.

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Document Details

Document Type
Technical Report
Publication Date
Oct 31, 1961
Accession Number
AD0271791

Entities

People

  • H. V. Weiss
  • W. H. Shipman

Organizations

  • Naval Radiological Defense Laboratory

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  • Air Platforms
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  • Acetic Acid
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  • Chemistry

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